sample_dickson1981

PUBLIC dataset: theoretical titration curve for TA
 determination as given in table 1 of Dickson1981 
 
 Meta-data: 
 <table><tr><td>
 x-value </td>
</tr><tr><td> mass of titrant added (in g) </td>
</tr><tr><td>
 y-value </td>
</tr><tr><td> pH measured on the free proton scale </td>
</tr></table>
 <table><tr><td>
 t </td>
<td> 25 </td>
</tr><tr><td> degC </td>
<td>
 S </td>
</tr><tr><td> 35 </td>
<td> </td>
</tr><tr><td>
 mass\_sample </td>
<td> 200 </td>
</tr><tr><td> g </td>
<td>
 conc\_titrant </td>
</tr><tr><td> 0.3000 </td>
<td> mol/kg-soln </td>
</tr><tr><td>
 TA </td>
<td> 0.00245 </td>
</tr><tr><td> mol/kg-soln </td>
<td>
 SumCO2 </td>
</tr><tr><td> 0.00220 </td>
<td> mol/kg-soln </td>
</tr><tr><td>
 SumBOH3 </td>
<td> 0.00042 </td>
</tr><tr><td> mol/kg-soln </td>
<td>
 SumH2SO4 </td>
</tr><tr><td> 0.02824 </td>
<td> mol/kg-soln </td>
</tr><tr><td>
 SumHF </td>
<td> 0.00007 </td>
</tr><tr><td> mol/kg-soln </td>
<td>
 K\_W </td>
</tr><tr><td> 4.32e-14 </td>
<td> (mol/kg-soln)*(mol/kg-soln) </td>
</tr><tr><td>
 K\_CO2 </td>
<td> 1.00e-6 </td>
</tr><tr><td> mol/kg-soln </td>
<td>
 K\_HCO3 </td>
</tr><tr><td> 8.20e-10 </td>
<td> mol/kg-soln </td>
</tr><tr><td>
 K\_BOH3 </td>
<td> 1.78e-9 </td>
</tr><tr><td> mol/kg-soln </td>
<td>
 K\_HSO4 </td>
</tr><tr><td> 1/1.23e1 </td>
<td> mol/kg-soln </td>
</tr><tr><td>
 K\_HF </td>
<td> 1/4.08e2 </td>
</tr><tr><td> mol/kg-soln </td>
<td>
 t </td>
</tr></table>

misc

Toolbox for the experimental aquatic chemist, focused on
acidification and CO2 air-water exchange. It contains all elements to
model the pH, the related CO2 air-water exchange, and
aquatic acid-base chemistry for an arbitrary marine,
estuarine or freshwater system. It contains a suite of tools for
sensitivity analysis, visualisation, modelling of chemical batches,
and can be used to build dynamic models of aquatic systems.
As from version 1.0-4, it also contains functions to calculate
the buffer factors.

sample_dickson1981: sample\_dickson1981

Description

Arguments

t	25
degC	S
35
mass\_sample	200
g	conc\_titrant
0.3000	mol/kg-soln
TA	0.00245
mol/kg-soln	SumCO2
0.00220	mol/kg-soln
SumBOH3	0.00042
mol/kg-soln	SumH2SO4
0.02824	mol/kg-soln
SumHF	0.00007
mol/kg-soln	K\_W
4.32e-14	(mol/kg-soln)*(mol/kg-soln)
K\_CO2	1.00e-6
mol/kg-soln	K\_HCO3
8.20e-10	mol/kg-soln
K\_BOH3	1.78e-9
mol/kg-soln	K\_HSO4
1/1.23e1	mol/kg-soln
K\_HF	1/4.08e2
mol/kg-soln	t